Frustrated Lewis pairs: reactivities of TMS protected amines and phosphines in the presence of B(C(6)F(5))(3).
نویسندگان
چکیده
TMS protected amines in combination with B(C(6)F(5))(3) were found to activate H(2) and this is followed by a cleavage of the N-Si bond and the generation of TMSH. A TMS protected phosphine on the other hand reacts rapidly with B(C(6)F(5))(3) to give the known compound tBu(2)P(C(6)F(4))B(C(6)F(5))(2) by a facile and efficient route.
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عنوان ژورنال:
- Dalton transactions
دوره 39 8 شماره
صفحات -
تاریخ انتشار 2010